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    沼气辅助固体氧化物电解池制合成气过程模拟与能量分析

    Process Simulation and Energy Analysis of Syngas Production in a Biogas-Assisted Solid Oxide Electrolysis Cell System

    • 摘要: 面向可持续航空燃料(Sustainable Aviation Fuel,SAF)费托合成前端的合成气需求,以CH4/CO2为主体的未深度脱碳沼气模拟气为阳极进料,建立沼气辅助固体氧化物电解池(Solid Oxide Electrolysis Cell,SOEC)制合成气系统模型。模型包括单电池电压与电化学反应速率计算、阳极平衡转化及换热分离过程,并采用电流–电压(I–V)、电化学阻抗谱(EIS)数据及文献工况进行分层校核。2500~4500 A·m−2范围内,模型电压平均绝对偏差为0.0095 V。温度由500 ℃升至700 ℃时,CH4转化率由73.8%提高至99.5%,含CO2合成气费托化学计量比(RFT)由0.916提高至0.999,制备单位目标合成气的综合能耗由2.66降至0.60 kWh·Nm−3。二维分析表明,温度为600至700 ℃、阳极H2O/CH4摩尔比为0.5至1.5,并在CH4/CO2摩尔比为2.6至3.3和电流密度为3000至4300 A·m−2的协同区域内运行时可兼顾CH4转化、合成气组成匹配和较低能耗。代表性工况下,前端制合成气能量效率为86.9%,热回收比例为45.0%。研究结果可为未深度脱碳沼气辅助SOEC制备费托合成气的工况筛选提供参考。

       

      Abstract: To optimize the upstream syngas production during the Fischer–Tropsch synthesis of sustainable aviation fuel, a system model was developed for a biogas-assisted solid oxide electrolysis cell (SOEC) using a non-upgraded biogas simulant mainly composed of CH4 and CO2 as the anode feed. The model included calculations of single-cell voltages and electrochemical reaction rates, anodic equilibrium conversion, heat exchange, and separation processes, and was evaluated at multiple levels using the I–V and EIS data together with the operating conditions reported in the literature. Within the current-density range of 2500–4500 A·m−2, the mean absolute deviation of the predicted cell voltage was 0.0095 V. Increasing the temperature from 500 to 700 ℃ resulted in an increase in the CH4 conversion from 73.8% to 99.5% and the Fischer–Tropsch stoichiometric ratio for CO2-containing syngas (RFT) from 0.916 to 0.999, accompanied by a decrease in the specific overall energy consumption of target syngas from 2.66 to 0.60 kWh·Nm−3 under the investigated conditions. Two-dimensional analysis showed that CH4conversion, syngas-composition matching, and low energy consumption can be balanced at 600–700 ℃ and anode H2O/CH4ratios of 0.5–1.5, and within the coupled CH4/CO2–current-density region of 2.6–3.3 and 3000–4300 A·m−2. Under the representative operating condition, the energy efficiency of the upstream syngas production was as high as 86.9% with a heat-recovery ratio of 45.0%. The results can provide a reference for operating-condition screening in Fischer–Tropsch syngas production using non-upgraded biogas-assisted SOECs.

       

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