高级检索

    活性煤浆中甲烷水合物动力学研究

    Kinetics study of methane hydrate formation in active coal slurry

    • 摘要: 实现水合物技术的规模化应用,关键在于提高其反应速率与储气密度。本研究将十二烷基硫酸钠(SDS)溶液与微米级煤粉混合,高速搅拌混合成活性煤浆。在压力为8.0 MPa、温度为274.15 K的环境下,研究煤粉质量分数为5.0 ~35.0%的活性煤浆中甲烷水合物生成动力学和储气性能。研究发现,所用煤粉具有丰富的微孔结构,可为水合物生成提供丰富的成核位点。煤粉质量分数为5.0%时,储气性能最佳,最大储气速率为9.3 cm3·cm–3·min–1,最大储气量为166.9 cm3·cm–3,达到90%最大储气量所需的时间(t90)为9.3 min。进一步研究能量密度发现,煤基水合物能量密度始终高于相同煤粉含量的传统煤水混合物。煤粉质量分数为30.0%的活性煤浆所形成的二元燃料具有最佳的能量密度表现。

       

      Abstract: The key to enabling the large-scale application of hydrate-based technology lies in enhancing the reaction rate and gas storage density. In this study, an active coal slurry was prepared by vigorously stirring a mixture of SDS solution and micron-sized coal powder. The kinetics and gas storage performance of methane hydrates were investigated in active coal slurries with coal concentrations ranging from 5.0 to 35.0 wt%, under conditions of 8.0 MPa and 274.15 K. The results indicated that the coal powder used has a rich microporous structure and a high specific surface area, which can provide abundant nucleation sites for the formation of hydrate. At a coal powder concentration of 5.0 wt%, the gas storage performance was optimal, achieving a maximum gas storage rate of 9.3 cm3·cm–3·min–1, a maximum gas storage capacity of 166.9 cm3·cm–3, and a time to reach 90% of the maximum capacity (t90) of 9.3 min. Further analysis of energy density indicates that coal-based hydrates consistently exhibit higher energy density than traditional coal-water mixtures at identical coal powder concentrations. Among these, the binary fuel prepared from active coal slurry at a concentration of 30.0 wt% demonstrates the optimal energy density performance.

       

    /

    返回文章
    返回