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    低温CO2甲烷化催化剂研究进展

    Research process on low-temperature CO2 methanation catalysts

    • 摘要: 本文系统性回顾了催化剂体系在低温CO2甲烷化领域中的研究进展,详细探讨了载体、助剂以及金属活性成分对催化剂性能的调控作用。在传统热催化体系中,Ni基催化剂因其优异的活性和低廉的成本被广泛研究。例如,经过改性的Mn-Ni/Al2O3催化剂在220 ℃的反应温度下,CO2转化率可达88.9%,CH4选择性接近100%。其次,在新型催化技术方面,本文详细综述了等离子体-催化协同体系和光热催化剂技术的研究进展。通过等离子体技术激活CO2分子,可以显著降低反应活化能。例如,在等离子体-催化协同体系中,Ni/Al2O3在150 ℃的反应温度下,CO2转化率为60%,CH4选择性为97%。此外,光热催化技术的引入进一步拓展了低温CO2甲烷化的反应路径,催化剂NiFeM(M=Al、Zr、Mg、Cr)在光照条件下的CO2转化率高达98%,CH4选择性为99%。这些新型技术的引入为低温CO2甲烷化提供了更广阔的应用前景。最后,结合当前研究现状,本文对CO2低温甲烷化领域的未来发展方向进行了展望,明确了当前需攻克的关键科学问题与技术难题,以期为该领域的研究提供参考。

       

      Abstract: This paper provides a review of the research progress in catalytic systems for low-temperature CO2 methanation, which focuses on the detail discussion of the regulation effect of supports, promoters, and metals as active species on catalyst performance. In conventional catalytic systems, Ni-based catalysts have been widely studied due to their excellent activity and low cost. For example, the modified Mn-Ni/Al2O3 catalyst could achieve a CO2 conversion of 88.9% and a CH4 selectivity close to 100% at a reaction temperature of 220 ℃. Secondly, in terms of new catalytic technologies, the paper provides a detailed overview of recent advances in plasma-catalytic synergetic systems and photothermal catalyst. By activating CO2 molecules through non-thermal plasma technology, the activation energy of the reaction can be significantly reduced. For example, in the plasma-catalytic synergetic system, the Ni/Al2O3 catalyst could achieve a CO2 conversion of 60% and a CH4 selectivity of 97% at a reaction temperature of 150 ℃. In addition, the introduction of photo-thermal catalytic technology further expands the reaction pathways for low-temperature CO2 methanation. The NiFeMM=Al, Zr, Mg, Cr) catalyst could achieve a CO2 conversion up to 98% and a CH4selectivity of 99% under light illumination. The introduction of these novel technologies offers a broader application prospect for low-temperature CO2 methanation. Finally, based on the current research status, the paper provides an outlook on the future development direction of the low-temperature CO2 methanation field, which clarifies the key scientific challenges and technical difficulties that need to be addressed and offers the valuable insights for further research in this area.

       

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