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    碳捕集系统中胺基吸收剂降解产物的形成和去除技术

    Formation and removal technologies of degradation products from amino absorbents in carbon capture systems

    • 摘要: 化学吸收碳捕集系统中胺基吸收剂的降解是影响系统吸收性能的重要因素。文中系统分析了吸收剂氧化与热降解机制,其中,胺基吸收剂在氧化环境下经自由基链式反应生成甲酸盐、草酸盐等热稳定性盐(HSS),在高温环境下氨基甲酸酯聚合形成2-恶唑烷酮等环状中性物质。针对其降解产物,文中探讨了4种去除方法的应用场景,并比较了这些方法的优点以及目前遇到的挑战。其中热回收法能同步去除HSS与中性物质,但胺损失率高,能耗大,还存在二次降解问题。离子交换法和电渗析法分别通过树脂吸附和电场迁移去除HSS,但树脂再生废水排放量大,电渗析膜容易出现堵塞问题。离子交换耦合电渗析法通过电-吸附协同实现高HSS去除率和低胺损失率,但中性物质仍残留在系统中。未来研究可以聚焦于耦合各种回收方法优势,推动胺基吸收剂在线净化技术的规模化应用。

       

      Abstract: The degradation products from amino absorbents in chemical absorption carbon capture systems is considered a significant factor affecting system performance. In this paper, oxidative and thermal degradation mechanisms of absorbents are systematically investigated. Amino absorbents generate heat stable salts (HSS) such as formic acid and oxalate via free radical chain reactions under oxidative conditions. The cyclic neutral components such as 2-oxazolidone are formed through carbamate polymerization under thermal conditions in the carbon capture systems. An overview of the four removal methods for its degradation products is presented, covering their application scenarios, advantages, and current challenges. Thermal reclaiming can simultaneously remove HSS and neutral components, but its application is limited by the high amine loss rate, high energy requirements and the risk of secondary degradation. Ion exchange and electrodialysis effectively eliminate HSS through resin adsorption and ion exchange membranes, respectively. However, the regeneration process of ion exchange resins can generate a significant volume of wastewater, and membranes of electrodialysis easily trigger fouling issues. An advanced technology coupling ion exchange with electrodialysis can effectively remove HSS, reduce amine loss and improve energy reduction through employing electro-adsorption mechanisms. However, neutral components could not be removed. Future research can focus on coupling the advantages of various reclaiming methods to promote the large-scale application of online purification technology of amino absorbents.

       

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