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    DPnB封端改性聚氨酯水分散体及助成膜性能

    Modification and Film-Forming Performance of DPnB Blocked Aqueous Polyurethane Dispersions

    • 摘要: 降低水性木器涂料中挥发性有机化合物(VOC)含量一直是研究的热点和难点,本文采用一元醇对聚氨酯预聚体封端改性,制备聚氨酯水分散体(b-PUD),探讨了封端剂种类、NCO封端度、NCO/OH摩尔比及软段聚多元醇种类等对b-PUD助成膜性能的影响。发现二丙二醇丁醚(DPnB)封端改性b-PUD的助成膜能力最好,且随封端度增加助成膜能力增强;聚醚二元醇为软段合成的b-PUD助成膜能力较聚酯二元醇好,以聚醚N210最好。当封端度80%,NCO/OH摩尔比1.5,制备b-PUD添加量为25%时,复配乳液的最低成膜温度(MFT)为2.9℃;该b-PUD制备水性透明底漆的VOC含量低至28 g·L-1,其涂膜具有优异的打磨性和高透明度。

       

      Abstract: Reducing volatile organic compounds (VOC) contents in waterborne wood coatings is challenging. Modified aqueous polyurethane dispersion (b-PUD) was prepared by blocking polyurethane prepolymer with monohydric alcohol. The effects of blocking agent category, NCO blocked percentage, NCO/OH molar ratio and soft segment polyol type on assistant-film-forming performance of b-PUD were discussed. The results show that b-PUD modified by dipropylene glycol butyl ether (DPnB) has the best assistant-film-forming ability which increases with the increase of blocked percentage. In addition, the assistant-film-forming ability of b-PUD with polyether glycol as the soft segment is better than that of polyester glycol, and polyether N210 shows the best performance. When NCO blocked percentage is 80%, molar ratio of NCO/OH is 1.5 and b-PUD adding percentage is 25%, the minimum film forming temperature (MFT) of the composite emulsion is 2.9℃ and the VOC content of the waterborne transparent primer based on b-PUD is 28 g·L-1. This coating has excellent sanding property and high transparency.

       

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