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    开式高温吸附热泵生成蒸汽系统的耐久性能研究

    Cyclic Durability of a High Temperature Open Adsorption Heat Pump for Steam Generation

    • 摘要: 实验研究了用于回收热水和热气中低品位余热生成高温蒸汽的开式吸附热泵系统的耐久性能。采用13X沸石-水工质对,反应器内填充320 g沸石,通入80℃热水和130℃热空气,生成191~264℃过热蒸汽。结果表明:系统生成蒸汽的质量约占总进水量的14.5%,蒸汽生成速率为4.87×10-5 kg(s)·kg(z)-1·s-1。15个连续循环结果显示,第一个循环所用沸石初始含水量较低,积分吸附热大,系统性能最优,最高蒸汽温度为264℃,系统温升为156℃,制热系数COPh(coefficient of performance for heating)达0.43,㶲效率COPex(exergy coefficient of performance)达0.54;其后14个循环系统温升为(94±3)℃,COPh为0.31~0.33,COPex为0.35~0.37。结果表明沸石微孔在高温高湿度下仍可保持结构完整,沸石吸水性能稳定,系统耐久性能良好。

       

      Abstract: Cyclic durability of an open adsorption heat pump system to generate high temperature steam using low-grade hot water and gas was experimentally tested. A 13X zeolite-water working pair was used, and 320 g zeolite was filled in the reactor. Superheated steam of 191~264℃ was generated from the system with input water of 80℃ and dry air of 130℃. The results show that the steam to input water mass ratio is 14.5%, and the steam generation rate is 4.87×10-5 kg(s)·kg(z)-1·s-1. The first cycle of a 15-cycle test shows the highest steam temperature of 264℃ and the temperature lift is 156℃, with COPh(coefficient of performance for heating) and COPex(exergy efficiency of performance) of 0.43 and 0.54, respectively. This is due to the lowest initial water content in zeolite and the highest integral adsorption heat. The subsequent 14 cycles show steady performance with gross temperature lift of 94±3℃, COPh of 0.31~0.33 and COPex of 0.35~0.37. It can be concluded that the nano-scale pores inside zeolite particles keeps functional under high temperature and high humidity conditions. Water adsorption ability of the zeolite remains stable with good durability.

       

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